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subsequent changes that this induces in scattering rates, exciton energies, impurity energies, etc are the fundamental changes introduced to the phonon modes It can be appreciated that such changes are likely as the bulk LO phonon in GaAs has an energy of around 36 meV while in AlAs it is closer to 50 meV Hence, forming a superlattice with alternating layers of GaAs and AlAs is going to have some effect on the phonon energies Various models have been put forward to account for this change in symmetry At one end of the scale, some models consider each semiconductor layer as a continuum of material with macroscopic-like properties, namely the Dielectric Continuum model, (see for example [178]), or the Hydrodynamic model, (see for example [182]) Alternative approaches have considered the allowed vibrational modes calculated directly from the viewpoint of individual atomic potentials (see for example, [183]) See Adachi [14], p.

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70, for an introduction Such improved models for phonons in heterostructures lead to modes which are confined to the individual semiconductor layers confined modes while some propagate along boundaries between the layers the so-called interface modes Recent work has shown that while the electron-phonon scattering rates from these individual modes are quite different, the total rate from all of the modes collectively is quite similar to that from bulk phonons (see Kinsler et al [184]) However, this is still a very active area of research and future developments will need to be monitored 913 CARRIER-CARRIER SCATTERING Fermi's Golden Rule describes the lifetime of a particle in a particular state with respect to scattering by a time-varying potential For phonon scattering, this harmonic potential is derived from the phonon wave function, which is itself a travelling wave.

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